I'm moving to the Hondon Valley as anybody any idea what is the best ISP (Broadband) to use in Spain?

As your line will almost certainly be a telefonica one, then I can only suggest telefonica, most of the people here use them, and, even though they are not briliant, they are the best. Certainly if you want to use a different provider, then you line has to come from telefonica, and I suspect that lines for people who want to sign up to telefonica get a great priority over those just wanting the connection.